All Papers

2020

Wasielewski, M. R.; Forbes, M. D. E.; Frank, N. L.; Kowalski, K.; Scholes, G. D.; Yuen-Zhou, J.; Baldo, M. A.; Freedman, D. E.; Goldsmith, R. H.; Goodson, T.; Kirk, M. L.; McCusker, J. K.; Ogilvie, J. P.; Shultz, D. A.; Stoll, S.; Whaley, K. B., Exploiting chemistry and molecular systems for quantum information science. Nature Reviews Chemistry 2020. 10.1038/s41570-020-0200-5

Roch, L. M.; Saikin, S. K.; Hase, F.; Friederich, P.; Goldsmith, R. H.; Leon, S.; Aspuru-Guzik, A., From Absorption Spectra to Charge Transfer in Nanoaggregates of Oligomers with Machine Learning. ACS Nano 2020, 14 (6), 6589-6598. 10.1021/acsnano.0c00384

Alkmin, S.; Brodziski, R.; Simon, H.; Hinton, D.; Goldsmith, R. H.; Patankar, M.; Campagnola, P. J., Role of collagen fiber morphology on ovarian cancer cell migration using image-based models of the extracellular matrix. Cancers 2020, 12 (6). 10.3390/cancers12061390

White, D. S.; Goldschen-Ohm, M. P.; Goldsmith, R. H.; Chanda, B., Top-down machine learning approach for high-throughput single-molecule analysis. Elife 2020, 9. 10.7554/eLife.53357

Cavell, A. C.; Krasecki, V. K.; Li, G. P.; Sharma, A.; Sun, H.; Thompson, M. P.; Forman, C. J.; Guo, S. Y.; Hickman, R. J.; Parrish, K. A.; Aspuru-Guzik, A.; Cronin, L.; Gianneschi, N. C.; Goldsmith, R. H., Optical monitoring of polymerizations in droplets with high temporal dynamic range. Chemical Science 2020, 11 (10), 2647-2656. 10.1039/c9sc05559b

 

Pan, F.; Smith, K. C.; Nguyen, H. L.; Knapper, K. A.; Masiello, D. J.; Goldsmith, R. H., Elucidating Energy Pathways through Simultaneous Measurement of Absorption and Transmission in a Coupled Plasmonic-Photonic Cavity. Nano Lett 2020, 20 (1), 50-58. 10.1021/acs.nanolett.9b02796

2019

Ying, L.; Zhou, M.; Mattei, M.; Liu, B. Y.; Campagnola, P.; Goldsmith, R. H.; Yu, Z. F., Extended Range of Dipole-Dipole Interactions in Periodically Structured Photonic Media. Phys. Rev. Lett. 2019, 123 (17). 10.1103/PhysRevLett.123.173901

Rea, M. T.; Pan, F.; Horak, E. H.; Knapper, K. A.; Nguyen, H. L.; Vollbrecht, C. H.; Goldsmith, R. H., Investigating the Mechanism of Post-Treatment on PEDOT/PSS via Single-Particle Absorption Spectroscopy. Journal of Physical Chemistry C 2019, 123 (51), 30781-30790. 10.1021/acs.jpcc.9b06259

Hogan, L. T.; Horak, E. H.; Ward, J. M.; Knapper, K. A.; Chormaic, S. N.; Goldsmith, R. H., Toward Real-Time Monitoring and Control of Single Nanoparticle Properties with a Microbubble Resonator Spectrometer. ACS Nano 2019, 13 (11), 12743-12757. 10.1021/acsnano.9b04702

Foote, A. K.; Manger, L. H.; Holden, M. R.; Margittai, M.; Goldsmith, R. H., Time-resolved multirotational dynamics of single solution-phase tau proteins reveals details of conformational variation. Phys. Chem. Chem. Phys 2019, 21 (4), 1863-1871. 10.1039/c8cp06971a

Alkmin, S.; Brodziski, R.; Simon, H.; Hinton, D.; Goldsmith, R. H.; Patankar, M.; Campagnola, P. J., Migration dynamics of ovarian epithelial cells on micro-fabricated image-based models of normal and malignant stroma. Acta Biomaterialia 2019, 100, 92-104. 10.1016/j.actbio.2019.09.037

2018

Wan, C.; Horak, E. H.; King, J.; Salman, J.; Zhang, Z.; Zhou, Y.; Roney, P.; Gundlach, B.; Ramanathan, S.; Goldsmith, R. H.; Kats, M. A., Limiting Optical Diodes Enabled by the Phase Transition of Vanadium Dioxide. ACS Photonics 2018, 5 (7), 2688-2692. 10.1021/acsphotonics.8b00313

Robinson, M. E.; Ng, J. D.; Zhang, H. L.; Buchman, J. T.; Shenderova, O. A.; Haynes, C. L.; Ma, Z. Q.; Goldsmith, R. H.; Hamers, R. J., Optically Detected Magnetic Resonance for Selective Imaging of Diamond Nanoparticles. Anal. Chem. 2018, 90 (1), 769-776. 10.1021/acs.analchem.7b03157

Knapper, K. A.; Pan, F.; Rea, M. T.; Horak, E. H.; Rogers, J. D.; Goldsmith, R. H., Single-particle photothermal imaging via inverted excitation through high-Q all-glass toroidal microresonators. Optics Express 2018, 26 (19), 25020-25030. 10.1364/oe.26.025020

Knapper, K. A.; Horak, E. H.; Vollbrecht, C. H.; Heylman, K. D.; Goldsmith, R. H., Phase-sensitive photothermal imaging of ultrahigh-Q polyoxide toroidal microresonators. Appl. Phys. Lett. 2018, 113 (23). 10.1063/1.5055889

 

Horak, E. H.; Rea, M. T.; Heylman, K. D.; Gelbwaser-Klimovsky, D.; Saikin, S. K.; Thompson, B. J.; Kohler, D. D.; Knapper, K. A.; Wei, W.; Pan, F.; Gopalan, P.; Wright, J. C.; Aspuru-Guzik, A.; Goldsmith, R. H., Exploring Electronic Structure and Order in Polymers via Single-Particle Microresonator Spectroscopy. Nano Lett 2018, 18 (3), 1600-1607. 10.1021/acs.nanolett.7b04211

Horak, E. H.; Goldsmith, R. H., Drumming up single-molecule beats. Proc. Natl. Acad. Sci. U. S. A. 2018, 115 (44), 11115-11117. 10.1073/pnas.1815764115

Hinton, D. A.; Ng, J. D.; Sun, J.; Lee, S.; Saikin, S. K.; Logsdon, J.; White, D. S.; Marquard, A. N.; Cavell, A. C.; Krasecki, V. K.; Knapper, K. A.; Lupo, K. M.; Wasielewski, M. R.; Aspuru-Guzik, A.; Biteen, J. S.; Gopalan, P.; Goldsmith, R. H., Mapping Forbidden Emission to Structure in Self-Assembled Organic Nanoparticles. J. Am. Chem. Soc. 2018, 140 (46), 15827-15841. 10.1021/jacs.8b09149

2017

Thakkar, N.; Rea, M. T.; Smith, K. C.; Heylman, K. D.; Quillin, S. C.; Knapper, K. A.; Horak, E. H.; Masiello, D. J.; Goldsmith, R. H., Sculpting Fano Resonances To Control Photonic-Plasmonic Hybridization. Nano Lett 2017, 17 (11), 6927-6934. 10.1021/acs.nanolett.7b03332

 

Padilla, N. A.; Rea, M. T.; Foy, M.; Upadhyay, S. P.; Desrochers, K. A.; Derus, T.; Knapper, K. A.; Hunter, N. H.; Wood, S.; Hinton, D. A.; Cavell, A. C.; Masias, A. G.; Goldsmith, R. H., Tracking Lithium Ions via Widefield Fluorescence Microscopy for Battery Diagnostics. ACS Sensors 2017, 2 (7), 903-908. 10.1021/acssensors.7b00087

Marquard, A. N.; Slaymaker, L. E.; Hamers, R. J.; Goldsmith, R. H., Investigation of activity, stability, and degradation mechanism of surface-supported Pd-PEPPSI complexes for Suzuki-Miyaura coupling. Molecular Catalysis 2017, 429, 10-17. 10.1016/j.molcata.2016.12.001

Manger, L. H.; Rowley, M. B.; Fu, Y. P.; Foote, A. K.; Rea, M. T.; Wood, S. L.; Jin, S.; Wright, J. C.; Goldsmith, R. H., Global Analysis of Perovskite Photophysics Reveals Importance of Geminate Pathways. Journal of Physical Chemistry C 2017, 121 (2), 1062-1071. 10.1021/acs.jpcc.6b11547

 

Manger, L. H.; Foote, A. K.; Wood, S. L.; Holden, M. R.; Heylman, K. D.; Margittai, M.; Goldsmith, R. H., Revealing Conformational Variants of Solution-Phase Intrinsically Disordered Tau Protein at the Single-Molecule Level. Angew. Chem.-Int. Edit 2017, 56 (49), 15584-15588. 10.1002/anie.201708242

Heylman, K. D.; Knapper, K. A.; Horak, E. H.; Rea, M. T.; Vanga, S. K.; Goldsmith, R. H., Optical Microresonators for Sensing and Transduction: A Materials Perspective. Adv. Mater 2017, 29 (30). 10.1002/adma.201700037

Goldschen-Ohm, M. P.; White, D. S.; Klenchin, V. A.; Chanda, B.; Goldsmith, R. H., Observing Single-Molecule Dynamics at Millimolar Concentrations. Angew. Chem.-Int. Edit 2017, 59 (9), 2399-2402. 10.1002/anie.201612050

Fu, Y. P.; Rea, M. T.; Chen, J.; Morrow, D. J.; Hautzinger, M. P.; Zhao, Y. Z.; Pan, D. X.; Manger, L. H.; Wright, J. C.; Goldsmith, R. H.; Jin, S., Selective Stabilization and Photophysical Properties of Metastable Perovskite Polymorphs of CsPbl(3) in Thin Films. Chem. Mat 2017, 29 (19), 8385-8394. 10.1021/acs.chemmater.7b02948

2016

Ng, J. D.; Upadhyay, S. P.; Marquard, A. N.; Lupo, K. M.; Hinton, D. A.; Padilla, N. A.; Bates, D. M.; Goldsmith, R. H., Single-Molecule Investigation of Initiation Dynamics of an Organometallic Catalyst. J. Am. Chem. Soc. 2016, 138 (11), 3876-3883. 10.1021/jacs.6b00357

 

Lupo, K. M.; Hinton, D. A.; Ng, J. D.; Padilla, N. A.; Goldsmith, R. H., Probing Heterogeneity and Bonding at Silica Surfaces through Single-Molecule Investigation of Base-Mediated Linkage Failure. Langmuir 2016, 32 (36), 9171-9179. 10.1021/acs.langmuir.6b02456

Knapper, K. A.; Heylman, K. D.; Horak, E. H.; Goldsmith, R. H., Chip-scale fabrication of high-Q all-glass toroidal microresonators for single-particle label-free imaging. Adv. Mater 2016, 28 (15), 2945-2950. 10.1002/adma.201504976

 

Heylman, K. D.; Thakkar, N.; Horak, E. H.; Quillin, S. C.; Cherqui, C.; Knapper, K. A.; Masiello, D. J.; Goldsmith, R. H., Optical microresonators as single-particle absorption spectrometers. Nature Photonics 2016, 10 (12), 788-+. 10.1038/nphoton.2016.217

Goldschen-Ohm, M. P.; Klenchin, V. A.; White, D. S.; Cowgill, J. B.; Cui, Q.; Goldsmith, R. H.; Chanda, B., Structure and dynamics underlying elementary ligand binding events in human pacemaking channels. eLife 2016, 5, e20797. 10.7554/eLife.20797

Gelbwaser-Klimovsky, D.; Saikin, S. K.; Goldsmith, R. H.; Aspuru-Guzik, A., Optical Spectra of p-Doped PEDOT Nanoaggregates Provide Insight into the Material Disorder. ACS Energy Letters 2016, 1, 1100-1105. 10.1021/acsenergylett.6b00443

Dai, J.; Fu, Y. P.; Manger, L. H.; Rea, M. T.; Hwang, L.; Goldsmith, R. H.; Jin, S., Carrier Decay Properties of Mixed Cation Formamidinium-Methylammonium Lead Iodide Perovskite HC(NH2)(2) (1-X) CH3NH3 (x)PbI3 Nanorods. Journal of Physical Chemistry Letters 2016, 7 (24), 5036-5043. 10.1021/acs.jpclett.6b01958

2013-2015

Upadhyay, S. P.; Lupo, K. M.; Marquard, A. N.; Ng, J. D.; Bates, D. M.; Goldsmith, R. H., Fluorescent Dendrimeric Molecular Catalysts Demonstrate Unusual Scaling Behavior at the Single-Molecule Level. Journal of Physical Chemistry C 2015, 119 (34), 19703-19714. 10.1021/acs.jpcc.5b06562

Heylman, K. D.; Knapper, K. A.; Goldsmith, R. H., Photothermal Microscopy of Nonluminescent Single Particles Enabled by Optical Microresonators. Journal of Physical Chemistry Letters 2014, 5 (11), 1917-1923. 10.1021/jz500781g

Heylman, K. D.; Goldsmith, R. H., Photothermal mapping and free-space laser tuning of toroidal optical microcavities. Appl. Phys. Lett. 2013, 103 (21).  10.1063/1.4833539

2005-2012

Wang, Q.; Goldsmith, R. H.; Jiang, Y.; Bockenhauer, S. D.; Moerner, W. E., Probing single biomolecules in solution using the anti-Brownian electrokinetic (ABEL) trap. Acc. Chem. Res. 2012, 45 (11), 1955-1964. 10.1021/ar200304t

Goldsmith, R. H.; Tabares, L. C.; Kostrz, D.; Dennison, C.; Aartsma, T. J.; Canters, G. W.; Moerner, W. E., Redox cycling and kinetic analysis of single molecules of solution-phase nitrite reductase. Proc. Natl. Acad. Sci. U. S. A. 2011, 108 (42), 17269-17274. 10.1073/pnas.1113572108

Goldsmith, R. H.; Moerner, W. E., Watching conformational- and photodynamics of single fluorescent proteins in solution. Nature Chemistry 2010, 2 (3), 179-186. 10.1038/nchem.545

Solomon, G. C.; Andrews, D. Q.; Hansen, T.; Goldsmith, R. H.; Wasielewski, M. R.; Van Duyne, R. P.; Ratner, M. A., Understanding quantum interference in coherent molecular conduction. J. Chem. Phys. 2008, 129 (5). 10.1063/1.2958275

Solomon, G. C.; Andrews, D. Q.; Goldsmith, R. H.; Hansen, T.; Wasielewski, M. R.; Van Duyne, R. P.; Ratner, M. A., Quantum Interference in Acyclic Systems: Conductance of Cross-Conjugated Molecules. J. Am. Chem. Soc. 2008, 130 (51), 17301-17308. 10.1021/ja8044053

Goldsmith, R. H.; Vura-Weis, J.; Scott, A. M.; Borkar, S.; Sen, A.; Ratner, M. A.; Wasielewski, M. R., Unexpectedly similar charge transfer rates through benzo-annulated bicyclo 2.2.2 octanes. J. Am. Chem. Soc. 2008, 130 (24), 7659-7669. 10.1021/ja8004623

Goldsmith, R. H.; DeLeon, O.; Wilson, T. M.; Finkelstein-Shapiro, D.; Ratner, M. A.; Wasielewski, M. R., Challenges in distinguishing superexchange and hopping mechanisms of intramolecular charge transfer through fluorene ligomers. J. Phys. Chem. A 2008, 112 (19), 4410-4414. 10.1021/jp801084v

Andrews, D. Q.; Solomon, G. C.; Goldsmith, R. H.; Hansen, T.; Wasielewski, M. R.; Van Duyne, R. P.; Ratner, M. A., Quantum Interference: The Structural Dependence of Electron Transmission through Model Systems and Cross-Conjugated Molecules. Journal of Physical Chemistry C 2008, 112 (43), 16991-16998. 10.1021/jp805588m

Kelley, R. F.; Goldsmith, R. H.; Wasielewski, M. R., Ultrafast energy transfer within cyclic self-assembled chlorophyll tetramers. J. Am. Chem. Soc. 2007, 129 (20), 6384-+. 10.1021/ja071362a

Goldsmith, R. H.; Wasielewski, M. R.; Ratner, M. A., Scaling laws for charge transfer in multiply bridged donor/acceptor molecules in a dissipative environment. J. Am. Chem. Soc. 2007, 129 (43), 13066-13071. 10.1021/ja073589b

Weiss, E. A.; Katz, G.; Goldsmith, R. H.; Wasielewski, M. R.; Ratner, M. A.; Kosloff, R.; Nitzan, A., Electron transfer mechanism and the locality of the system-bath interaction: A comparison of local, semilocal, and pure dephasing models. J. Chem. Phys. 2006, 124 (7). 10.1063/1.2168457

Goldsmith, R. H.; Wasielewski, M. R.; Ratner, M. A., Electron transfer in multiply bridged donor-acceptor molecules: Dephasing and quantum coherence. J. Phys. Chem. B 2006, 110 (41), 20258-20262. 10.1021/jp0639187

Goldsmith, R. H.; Sinks, L. E.; Kelley, R. F.; Betzen, L. J.; Liu, W. H.; Weiss, E. A.; Ratner, M. A.; Wasielewski, M. R., Wire-like charge transport at near constant bridge energy through fluorene oligomers. Proc. Natl. Acad. Sci. U. S. A. 2005, 102 (10), 3540-3545. 10.1073/pnas.0408940102